2023-077 - Thermally Robust, Rapid-Reversible Hydrogel Materials

Description:

Background 

Thermoresponsive hydrogels are attractive for injectable wound closure and other in situ forming applications because they can be applied as free-flowing liquids at low temperature and then gel near physiological temperatures. Their practical use, however, is limited by slow or incomplete gel-to-sol recovery after exposure to elevated storage temperatures, especially for higher molecular weight and higher concentration formulations.

Technology Description

USC researchers have developed a hydrogel that improves the reversibility of thermoresponsive sealants by loading the hydrogel into a high surface area open-cell foam host. The approach reduces domain size and accelerates solvation during cooling. The strongest performance was observed with medical-grade polyurethane foam, which produced nearly quantitative recovery and about a 10-fold improvement in recovery relative to hydrogel stored without foam. Importantly, the method improves recoverability without degrading the core material properties.

Benefits 

10x improved recovery relative to hydrogels without foam
Reliable redispersion after thermal stress
Reduced irreversible phase separation during storage
Low-cost and compatible with syringe-based delivery
Applicable to systems that require thermal robustness without sacrificing function

Stage of Development

lab prototype 

Applications 

Injectable would sealants
Agriculture and food-industry gel systems
 

Publications 

ACS Appl. Polym. Mater. 2023, 5, 4, 2525–2532 DOI: 10.1021/acsapm.2c02176

 

Patent Information:

  • Title: Systems and Methods to Accelerate Gel-Sol Transition for Thermoresponsive Hydrogels
  • App Type: Utility
  • Country: United States
  • Serial No.: 18/402,685
  • Patent No.:  
  • File Date: 1/2/2024
  • Issued Date:  
  • Expire Date:  
  • Patent Status: Patent Pending